BROWSE

Related Scientist

nanomat's photo.

nanomat
나노입자연구단
more info

ITEM VIEW & DOWNLOAD

Design of a trigonal halide superionic conductor by regulating cation order-disorder

DC Field Value Language
dc.contributor.authorYu, Seungju-
dc.contributor.authorNoh, Joohyeon-
dc.contributor.authorKim, Byunghoon-
dc.contributor.authorSong, Jun-Hyuk-
dc.contributor.authorOh, Kyungbae-
dc.contributor.authorYoo, Jaekyun-
dc.contributor.authorLee, Sunyoung-
dc.contributor.authorPark, Sung-O-
dc.contributor.authorKim, Wonju-
dc.contributor.authorKang, Byungwook-
dc.contributor.authorKil, Donghyun-
dc.contributor.authorKisuk Kang-
dc.date.accessioned2023-12-28T22:00:28Z-
dc.date.available2023-12-28T22:00:28Z-
dc.date.created2023-11-28-
dc.date.issued2023-11-
dc.identifier.issn0036-8075-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/14411-
dc.description.abstractLithium-metal-halides have emerged as a class of solid electrolytes that can deliver superionic conductivity comparable to that of state-of-the-art sulfide electrolytes, as well as electrochemical stability that is suitable for high-voltage (>4 volt) operations. We show that the superionic conduction in a trigonal halide, such as Li3MCl6 [where metal (M) is Y or Er], is governed by the in-plane lithium percolation paths and stacking interlayer distance. These two factors are inversely correlated with each other by the partial occupancy of M, serving as both a diffusion inhibitor and pillar for maintaining interlayer distance. These findings suggest that a critical range or ordering of M exists in trigonal halides, and we showcase the achievement of high ionic conductivity by adjusting the simple M ratio (per Cl or Li). We provide general design criteria for superionic trigonal halide electrolytes.-
dc.language영어-
dc.publisherAmerican Association for the Advancement of Science-
dc.titleDesign of a trigonal halide superionic conductor by regulating cation order-disorder-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid001138585700035-
dc.identifier.scopusid2-s2.0-85176345099-
dc.identifier.rimsid82147-
dc.contributor.affiliatedAuthorKisuk Kang-
dc.identifier.doi10.1126/science.adg6591-
dc.identifier.bibliographicCitationScience, v.382, no.6670, pp.573 - 579-
dc.relation.isPartOfScience-
dc.citation.titleScience-
dc.citation.volume382-
dc.citation.number6670-
dc.citation.startPage573-
dc.citation.endPage579-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Nanoparticle Research(나노입자 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse