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Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines

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Title
Controlling helical chirality of cobalt complexes by chirality transfer from vicinal diamines
Author(s)
Min-Seob Seo; Kiseong Kim; Hyunwoo Kim
Subject
cobalt complex, ; diamine, ; nitric oxide, ; article, ; chemical structure, ; chirality, ; isomerism, ; stereochemistry
Publication Date
2013-12
Journal
CHEMICAL COMMUNICATIONS, v.49, no.99, pp.11623 - 11625
Publisher
ROYAL SOC CHEMISTRY
Abstract
Stereoselective cis-trans isomerism of a CoIII-N 2O2 complex has been achieved by coordinating chiral vicinal diamines. The induced metal-centered helical chirality can be exploited for chirality amplification and asymmetric coordination chemistry. © 2013 The Royal Society of Chemistry.
URI
https://pr.ibs.re.kr/handle/8788114/1406
DOI
10.1039/c3cc46887a
ISSN
1359-7345
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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2013-12-25-ChemComm-Controlling helical chirality of cobalt.pdfDownload

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