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Open-Framework Iron Fluoride Phosphates Based on Chain, Trinuclear, and Tetranuclear Chain FeIIIBuilding Units: Crystal Structures and Magnetic Properties

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dc.contributor.authorJin, Yong-
dc.contributor.authorSuheon Lee-
dc.contributor.authorZhu, Tianyu-
dc.contributor.authorZhang, Xinan-
dc.contributor.authorYang, Haoming-
dc.contributor.authorChen, Dan-
dc.contributor.authorZhu, Wenxuan-
dc.contributor.authorChoi, Kwang-Yong-
dc.contributor.authorLü, Mingjeng-
dc.date.accessioned2022-07-29T07:43:29Z-
dc.date.available2022-07-29T07:43:29Z-
dc.date.created2022-07-11-
dc.date.issued2022-06-
dc.identifier.issn0020-1669-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/12021-
dc.description.abstractCopyright © 2022 American Chemical Society. We report the synthesis and characterization of a series of new open-framework iron fluoride-fluorophosphates based on linear, trinuclear, and tetranuclear chain FeIII building units. KFe2(PO3F)2F3 (I) consists of {Fe2(O3F)2F2}10- zigzag chains interconnected by P(O/F)4 tetrahedra forming a three-dimensional (3D) open framework. K2Fe(PO2.5F1.5)2F2 (II) is built up by {Fe(PO2.5F1.5)2F2}2- chains separated by K+ cation layers. The framework for K3Fe3(PO4)(PO3F)2F5 (III) contains two-dimensional {Fe3O4F4(PO3F)2}2- sheets, which are built from trimeric Fe-octahedra insulated by PO3F tetrahedra. The macroanionic framework of K3Fe4(PO4)2F9 (IV) comprises linear {Fe4O8F9}10- chains consisting of tetranuclear magnetic clusters of [Fe4O8F9]10- formed via corner-sharing fluorine atoms decorated with PO4 groups. The magnetic characterization of three iron fluorophosphates reveals diversified magnetism: S = 5/2 spin chains for I, antiferromagnetically coupled triangular Fe units for III, and coupled tetrahedral S = 5/2 spin chains for IV. IV shows strong geometric frustration thanks to its spin motifs of corner-shared tetrahedral clusters. © 2022 American Chemical Society.-
dc.language영어-
dc.publisherAmerican Chemical Society-
dc.titleOpen-Framework Iron Fluoride Phosphates Based on Chain, Trinuclear, and Tetranuclear Chain FeIIIBuilding Units: Crystal Structures and Magnetic Properties-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000814163200001-
dc.identifier.scopusid2-s2.0-85133033096-
dc.identifier.rimsid78453-
dc.contributor.affiliatedAuthorSuheon Lee-
dc.identifier.doi10.1021/acs.inorgchem.2c00997-
dc.identifier.bibliographicCitationInorganic Chemistry, v.61, no.24, pp.9257 - 9268-
dc.relation.isPartOfInorganic Chemistry-
dc.citation.titleInorganic Chemistry-
dc.citation.volume61-
dc.citation.number24-
dc.citation.startPage9257-
dc.citation.endPage9268-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.subject.keywordPlusMETAL PHOSPHATES-
dc.subject.keywordPlusTRANSITION-
dc.subject.keywordPlusCO-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusMN-
dc.subject.keywordPlusFLUOROPHOSPHATES-
dc.subject.keywordPlusSUSCEPTIBILITY-
dc.subject.keywordPlusSYSTEM-
dc.subject.keywordPlusCU-
dc.subject.keywordAuthorMETAL PHOSPHATES-
dc.subject.keywordAuthorTRANSITION-
dc.subject.keywordAuthorCO-
dc.subject.keywordAuthorCOMPLEXES-
dc.subject.keywordAuthorMN-
dc.subject.keywordAuthorFLUOROPHOSPHATES-
dc.subject.keywordAuthorSUSCEPTIBILITY-
dc.subject.keywordAuthorSYSTEM-
dc.subject.keywordAuthorCU-
Appears in Collections:
Center for Integrated Nanostructure Physics(나노구조물리 연구단) > 1. Journal Papers (저널논문)
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