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New classes of functionalized parylenes and poly(phenylene vinylene)s: Via coupling of dihaloxylyl diesters

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Title
New classes of functionalized parylenes and poly(phenylene vinylene)s: Via coupling of dihaloxylyl diesters
Author(s)
Jihong Lyu; Christopher W. Bielawski
Publication Date
2022-02
Journal
Polymer Chemistry, v.13, no.5, pp.613 - 621
Publisher
Royal Society of Chemistry
Abstract
© The Royal Society of Chemistry.New classes of poly(p-xylylene)s and poly(p-phenylene vinylene)s were synthesized and studied. The novel polymers differ from known variants of their kind in that the ethylene and vinylene repeat units are outfitted with ester groups, which can be readily modified through transesterification. The polymers were prepared by treating an appropriate dihalobenzene diester with either a reductant to afford the corresponding poly(p-xylylene) or a base to afford the corresponding poly(p-phenylene vinylene). Variation of the ester groups enabled a broad range of functional polymers to be prepared, including derivatives that are liquid crystalline, photoswitchable, water soluble or amenable to cycloaddition chemistry. This journal is
URI
https://pr.ibs.re.kr/handle/8788114/11300
DOI
10.1039/d1py01063h
ISSN
1759-9954
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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