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Nanoconfinement-Controlled Synthesis of Highly Active, Multinary Nanoplatelet Catalysts from Lamellar Magic-Sized Nanocluster Templates

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Title
Nanoconfinement-Controlled Synthesis of Highly Active, Multinary Nanoplatelet Catalysts from Lamellar Magic-Sized Nanocluster Templates
Author(s)
Woonhyuk Baek; Megalamane S. Bootharaju; Lorenz, Severin; Sanghwa Lee; Stolte, Sven; Fainblat, Rachel; Bacher, Gerd; Taeghwan Hyeon
Publication Date
2021-12
Journal
Advanced Functional Materials, v.31, no.49
Publisher
John Wiley and Sons Inc
Abstract
© 2021 Wiley-VCH GmbHMagic-sized semiconductor nanoclusters (MSCs) possessing intermediate stability are promising precursors for synthesizing low-dimensional nanostructures that cannot be achieved by direct methods. However, uncontrolled diffusion of MSCs in their colloidal-state poses challenges in utilizing them as precursors and/or templates for the controlled synthesis of nanomaterials. Herein, a nanoconfined diffusion-limited strategy to synthesize large CdSe nanoplatelets through the solid-state transformation of (CdSe)13 MSCs is designed, wherein MSCs serve as both precursors and lamellar bilayer templates. In sharp contrast, in the colloidal-state, these MSCs are grown to CdSe nanoribbons or nanorods. Furthermore, the nanoconfined route is used not only to transform (CdSe)13, Mn2+:(CdSe)13, and Mn2+:(Cd1−xZnxSe)13 MSCs but also to dope Cu+, producing Cu+:CdSe, Mn2+/Cu+:CdSe, Mn2+/Cu+:Cd1−xZnxSe nanoplatelets, respectively. The resulting multinary nanoplatelets with controlled compositions exhibit unique optical and magneto-optical properties through characteristic exciton transfer mechanisms. Furthermore, synergistic effects have made quinary Mn2+/Cu+:Cd0.5Zn0.5Se nanoplatelets efficient and reusable catalysts for chemical fixation of CO2 with epoxide (turnover frequency: ≈200/h) under mild conditions. This nanoconfined synthetic strategy paves the way to synthesize diverse shape-controlled multi-component nanostructures for optoelectronic and other catalytic applications.
URI
https://pr.ibs.re.kr/handle/8788114/10980
DOI
10.1002/adfm.202107447
ISSN
1616-301X
Appears in Collections:
Center for Nanoparticle Research(나노입자 연구단) > 1. Journal Papers (저널논문)
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