BROWSE

Related Scientist

Tian, Huang's photo.

Tian, Huang
첨단연성물질 연구단
more info

ITEM VIEW & DOWNLOAD

Reply to Comment on "Using NMR to Test Molecular Mobility during a Chemical Reaction"

Cited 0 time in webofscience Cited 0 time in scopus
13 Viewed 0 Downloaded
Title
Reply to Comment on "Using NMR to Test Molecular Mobility during a Chemical Reaction"
Author(s)
Tian Huang; Wang, Huan; Steve Granick
Publication Date
2021-06
Journal
Journal of Physical Chemistry Letters, v.12, no.24, pp.5744 - 5747
Publisher
American Chemical Society
Abstract
Reports of boosted diffusion during chemical and enzymatic reactions have inspired a loyal community of scientists who find them so counterintuitive that they must be artifact. This second Comment on the subject by these authors is about technicalities of how to analyze data we deposited online regarding J. Phys. Chem. Lett. 2021 12, 2370 and Science 2020 369, 537. Now that their own data is also online, one apparent discrepancy can be resolved: we demonstrate that the authors' data agrees with ours because their first Comment on this subject reported only truncated short-time excerpts of the longer time series they deposited online (zenodo.org/record/4628353). This second Comment adds five additional objections, four of which are too technical to change the qualitative conclusion. The fifth objection errs because it omits recognizing intermediate states of the click reaction during which one reactant complexes with the catalyst to form an object of larger size. Elsewhere we analyzed in great detail the respective influences of boosted diffusion and this hydrodynamic effect (DOI: 10.26434/chemrxiv.14740563.v1). The factual evidence and reasoning in this Reply strongly support this laboratory's earlier conclusions regarding boosted diffusion during common chemical reactions.
URI
https://pr.ibs.re.kr/handle/8788114/10444
DOI
10.1021/acs.jpclett.1c01312
ISSN
1948-7185
Appears in Collections:
Center for Soft and Living Matter(첨단연성물질 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
There are no files associated with this item.

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse