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Jeon, Hyun Ji
분자활성 촉매반응 연구단
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N-Chloro- N-sodio-carbamates as a Practical Amidating Reagent for Scalable and Sustainable Amidation of Aldehydes under Visible Light

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Title
N-Chloro- N-sodio-carbamates as a Practical Amidating Reagent for Scalable and Sustainable Amidation of Aldehydes under Visible Light
Author(s)
Hyun Ji Jeon; Wongyu Lee; Sangwon Seo; Sukbok Chang
Publication Date
2021-05
Journal
Organic Process Research and Development, v.25, no.5, pp.1176 - 1183
Publisher
American Chemical Society
Abstract
© 2021 American Chemical Society. All rights reserved.Herein, we describe the scalability and sustainability investigations toward the visible light-mediated amidation of aldehydes with N-chloro-N-sodio-carbamates. The practicality credentials of N-chloro-N-sodio-carbamates for their use in multigram scale amidation reactions are proven by scale-up productions and thermogravimetric analysis. The described amidation, which was previously hampered in sustainability perspectives by the use of α,α,α-trifluorotoluene solvent, is now improved through re-optimizations using ethyl acetate as an alternative green solvent. The generality of multigram scale amidations is demonstrated by the conversion of a selected list of aldehydes, in which the corresponding amides can be isolated in high purity without the need for special purification procedures.
URI
https://pr.ibs.re.kr/handle/8788114/9894
DOI
10.1021/acs.oprd.1c00054
ISSN
1083-6160
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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