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Jeon, Hyun Ji
분자활성 촉매반응 연구단
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N-Chloro- N-sodio-carbamates as a Practical Amidating Reagent for Scalable and Sustainable Amidation of Aldehydes under Visible Light

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dc.contributor.authorHyun Ji Jeon-
dc.contributor.authorWongyu Lee-
dc.contributor.authorSangwon Seo-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2021-07-12T01:30:03Z-
dc.date.accessioned2021-07-12T01:30:03Z-
dc.date.available2021-07-12T01:30:03Z-
dc.date.available2021-07-12T01:30:03Z-
dc.date.created2021-07-07-
dc.date.issued2021-05-
dc.identifier.issn1083-6160-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/9894-
dc.description.abstract© 2021 American Chemical Society. All rights reserved.Herein, we describe the scalability and sustainability investigations toward the visible light-mediated amidation of aldehydes with N-chloro-N-sodio-carbamates. The practicality credentials of N-chloro-N-sodio-carbamates for their use in multigram scale amidation reactions are proven by scale-up productions and thermogravimetric analysis. The described amidation, which was previously hampered in sustainability perspectives by the use of α,α,α-trifluorotoluene solvent, is now improved through re-optimizations using ethyl acetate as an alternative green solvent. The generality of multigram scale amidations is demonstrated by the conversion of a selected list of aldehydes, in which the corresponding amides can be isolated in high purity without the need for special purification procedures.-
dc.description.uri1-
dc.language영어-
dc.publisherAmerican Chemical Society-
dc.titleN-Chloro- N-sodio-carbamates as a Practical Amidating Reagent for Scalable and Sustainable Amidation of Aldehydes under Visible Light-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000656057000007-
dc.identifier.scopusid2-s2.0-85106438275-
dc.identifier.rimsid75988-
dc.contributor.affiliatedAuthorHyun Ji Jeon-
dc.contributor.affiliatedAuthorWongyu Lee-
dc.contributor.affiliatedAuthorSangwon Seo-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1021/acs.oprd.1c00054-
dc.identifier.bibliographicCitationOrganic Process Research and Development, v.25, no.5, pp.1176 - 1183-
dc.citation.titleOrganic Process Research and Development-
dc.citation.volume25-
dc.citation.number5-
dc.citation.startPage1176-
dc.citation.endPage1183-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.subject.keywordPlusCHEMISTRY RESEARCH AREAS-
dc.subject.keywordPlusAMIDE BOND FORMATION-
dc.subject.keywordPlusRADICALS-
dc.subject.keywordPlusPERSPECTIVE-
dc.subject.keywordAuthoraldehyde-
dc.subject.keywordAuthoramidation-
dc.subject.keywordAuthorAmide-
dc.subject.keywordAuthorphotochemical transformation-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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