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분자활성 촉매반응 연구단
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Oxidatively Induced Reductive Elimination for Methyl Group Transfer via Isolable Transmetalation Complexes

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Title
Oxidatively Induced Reductive Elimination for Methyl Group Transfer via Isolable Transmetalation Complexes
Author(s)
Jinwoo Kim; Seongho Jin; Dongwook Kim; Sukbok Chang
Publication Date
2021-02
Journal
Bulletin of the Korean Chemical Society, v.42, no.3, pp.529 - 532
Publisher
대한화학회
Abstract
Herein, we describe the mechanistic details on the oxidatively induced reductive elimination of isolated methyl iridium and ruthenium metallacycle complexes. It was demonstrated that the otherwise challenging CC bond formation is indeed facilitated by external oxidation, being enabled under mild conditions. Computational analyses supported the proposed high-valent pathway, where the energy barrier for reductive elimination significantly decreases upon the metallic oxidation to facilitate the desired CC bond formation.
URI
https://pr.ibs.re.kr/handle/8788114/9315
DOI
10.1002/bkcs.12235
ISSN
0253-2964
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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