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분자활성촉매반응연구단
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Oxidatively Induced Reductive Elimination for Methyl Group Transfer via Isolable Transmetalation Complexes

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dc.contributor.authorJinwoo Kim-
dc.contributor.authorSeongho Jin-
dc.contributor.authorDongwook Kim-
dc.contributor.authorSukbok Chang-
dc.date.accessioned2021-04-06T06:30:05Z-
dc.date.accessioned2021-04-06T06:30:05Z-
dc.date.available2021-04-06T06:30:05Z-
dc.date.available2021-04-06T06:30:05Z-
dc.date.created2021-02-26-
dc.date.issued2021-03-
dc.identifier.issn0253-2964-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/9315-
dc.description.abstractHerein, we describe the mechanistic details on the oxidatively induced reductive elimination of isolated methyl iridium and ruthenium metallacycle complexes. It was demonstrated that the otherwise challenging CC bond formation is indeed facilitated by external oxidation, being enabled under mild conditions. Computational analyses supported the proposed high-valent pathway, where the energy barrier for reductive elimination significantly decreases upon the metallic oxidation to facilitate the desired CC bond formation.-
dc.description.uri1-
dc.language영어-
dc.publisher대한화학회-
dc.titleOxidatively Induced Reductive Elimination for Methyl Group Transfer via Isolable Transmetalation Complexes-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000614603400001-
dc.identifier.scopusid2-s2.0-85100355629-
dc.identifier.rimsid74781-
dc.contributor.affiliatedAuthorJinwoo Kim-
dc.contributor.affiliatedAuthorSeongho Jin-
dc.contributor.affiliatedAuthorDongwook Kim-
dc.contributor.affiliatedAuthorSukbok Chang-
dc.identifier.doi10.1002/bkcs.12235-
dc.identifier.bibliographicCitationBulletin of the Korean Chemical Society, v.42, no.3, pp.529 - 532-
dc.citation.titleBulletin of the Korean Chemical Society-
dc.citation.volume42-
dc.citation.number3-
dc.citation.startPage529-
dc.citation.endPage532-
dc.type.docTypeArticle-
dc.description.journalClass1-
dc.description.isOpenAccessN-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.description.journalRegisteredClasskci-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.subject.keywordAuthorReductive elimination-
dc.subject.keywordAuthorHigh-valent pathway-
dc.subject.keywordAuthorC-C bond formation-
dc.subject.keywordAuthorMetallacycle-
dc.subject.keywordAuthorMethylation-
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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