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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Ni-Catalyzed Intermolecular C(sp3)-H Amidation Tuned by Bidentate Directing Groups
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- Title
- Ni-Catalyzed Intermolecular C(sp3)-H Amidation Tuned by Bidentate Directing Groups
- Author(s)
- Yeong Bum Kim; Joonghee Won; Jeonghyo Lee; Junho Kim; Bingwei Zhou; Jung-Woo Park; Mu-Hyun Baik; Sukbok Chang
- Publication Date
- 2021-03-05
- Journal
- ACS Catalysis, v.11, no.5, pp.3067 - 3072
- Publisher
- American Chemical Society
- Abstract
- We disclose herein a directing group-assisted nickel-catalyzed intermolecular C(sp3)-H amidation using organic azides as nitrene precursors. With the installation of an electronically tailored directing group, enhanced amidation efficiency was achieved. A series of experimental and computational studies suggested that a putative nickel(III)-nitrenoid species is a key intermediate in the C-N bond-forming process.
- ISSN
- 2155-5435
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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