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Ni-Catalyzed Intermolecular C(sp3)-H Amidation Tuned by Bidentate Directing Groups

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Title
Ni-Catalyzed Intermolecular C(sp3)-H Amidation Tuned by Bidentate Directing Groups
Author(s)
Yeong Bum Kim; Joonghee Won; Jeonghyo Lee; Junho Kim; Bingwei Zhou; Jung-Woo Park; Mu-Hyun Baik; Sukbok Chang
Publication Date
2021-01
Journal
ACS Catalysis, v.11, pp.3067 - 3072
Publisher
American Chemical Society
Abstract
We disclose herein a directing group-assisted nickel-catalyzed intermolecular C(sp3)-H amidation using organic azides as nitrene precursors. With the installation of an electronically tailored directing group, enhanced amidation efficiency was achieved. A series of experimental and computational studies suggested that a putative nickel(III)-nitrenoid species is a key intermediate in the C-N bond-forming process.
URI
https://pr.ibs.re.kr/handle/8788114/9294
DOI
10.1021/acscatal.1c00070
ISSN
2155-5435
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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