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분자활성 촉매반응 연구단
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Rhodium(III)-catalyzed C-C bond formation of quinoline N-oxides at the C-8 position under mild conditions Highly Cited Paper

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Title
Rhodium(III)-catalyzed C-C bond formation of quinoline N-oxides at the C-8 position under mild conditions
Author(s)
Jisu Jeong; Pitambar Patel; Heejun Hwang; Sukbok Chang
Publication Date
2014-09
Journal
ORGANIC LETTERS, v.16, no.17, pp.4598 - 4601
Publisher
AMER CHEMICAL SOC
Abstract
The Rh(III)-catalyzed C-8 selective direct alkylation and alkynylation of quinoline N-oxides has been developed. The reactions proceeded highly efficiently at room temperature over a broad range of substrates with excellent regioselectivity and functional group tolerance. This development demonstrates the synthetic utility of the N-oxide directing group as a stepping stone for remote C H functionalization of quinolines.
URI
https://pr.ibs.re.kr/handle/8788114/925
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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