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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to a P-Stereogenic Center
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- Title
- Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to a P-Stereogenic Center
- Author(s)
- Donghyeon Gwon; Donggun Lee; Jiyu Kim; Sehoon Park; Suk Bok Chang
- Subject
- asymmetric induction · CH functionalization ·chirality · iridium catalysis · phosphine oxides
- Publication Date
- 2014-09
- Journal
- CHEMISTRY-A EUROPEAN JOURNAL, v.20, no.39, pp.12421 - 12425
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- Direct CH amidation of arylphosphoryl compounds has been developed by using an IrIII catalyst system under mild conditions. A wide range of substrates could be employed with high functional-group tolerance. This procedure was successfully applied for the first time to the asymmetric reaction giving rise to a P-chirogenic center with a high diastereomeric ratio of up to 19:1 (90% de).
- ISSN
- 0947-6539
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
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