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분자활성 촉매반응 연구단
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Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to a P-Stereogenic Center

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Title
Iridium(III)-Catalyzed CH Amidation of Arylphosphoryls Leading to a P-Stereogenic Center
Author(s)
Donghyeon Gwon; Donggun Lee; Jiyu Kim; Sehoon Park; Suk Bok Chang
Publication Date
2014-09
Journal
CHEMISTRY-A EUROPEAN JOURNAL, v.20, no.39, pp.12421 - 12425
Publisher
WILEY-V C H VERLAG GMBH
Abstract
Direct CH amidation of arylphosphoryl compounds has been developed by using an IrIII catalyst system under mild conditions. A wide range of substrates could be employed with high functional-group tolerance. This procedure was successfully applied for the first time to the asymmetric reaction giving rise to a P-chirogenic center with a high diastereomeric ratio of up to 19:1 (90% de).
URI
https://pr.ibs.re.kr/handle/8788114/901
ISSN
0947-6539
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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