Nonlinear Dependence on Na+ Ions for the Binding Dynamics of Cucurbit[6]uril with the trans-1-Methyl-4-(4-hydroxystyryl)pyridinium Cation
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Tang, H. | - |
dc.contributor.author | Thomas, S.S. | - |
dc.contributor.author | Wolf, L. | - |
dc.contributor.author | Natarajan, P. | - |
dc.contributor.author | Young Ho Ko | - |
dc.contributor.author | Wilson, J. | - |
dc.contributor.author | Kimoon Kim | - |
dc.contributor.author | Bohne, C. | - |
dc.date.accessioned | 2020-12-22T02:23:16Z | - |
dc.date.accessioned | 2020-12-22T02:23:16Z | - |
dc.date.available | 2020-12-22T02:23:16Z | - |
dc.date.available | 2020-12-22T02:23:16Z | - |
dc.date.created | 2020-12-03 | - |
dc.date.issued | 2020-11 | - |
dc.identifier.issn | 1520-6106 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/7540 | - |
dc.description.abstract | © 2020 American Chemical Society. The binding dynamics of the trans-1-methyl-4-(4-hydroxystyryl)pyridinium cation (HSP+) to cucurbit[6]uril (CB[6]) in the presence of Na+ cations were studied to establish the effect of the relative concentrations of the system's components (HSP+, CB[6], and Na+) on these dynamics. The formation of the HSP+@CB[6] complex was temporally uncoupled from the photoisomerization of trans-HSP+, while a nonlinear effect of the Na+ cation concentration on the HSP+@CB[6] dynamics was observed. This nonlinearity is a consequence of Na+ having the opposite effect on the association and dissociation rate constants for the HSP+@CB[6] complex, creating a conceptual framework for using such nonlinearities to control multistep reactions in cucurbit[n]uril chemistry | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.title | Nonlinear Dependence on Na+ Ions for the Binding Dynamics of Cucurbit[6]uril with the trans-1-Methyl-4-(4-hydroxystyryl)pyridinium Cation | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000592732700024 | - |
dc.identifier.scopusid | 2-s2.0-85096152743 | - |
dc.identifier.rimsid | 73905 | - |
dc.contributor.affiliatedAuthor | Young Ho Ko | - |
dc.contributor.affiliatedAuthor | Kimoon Kim | - |
dc.identifier.doi | 10.1021/acs.jpcb.0c07554 | - |
dc.identifier.bibliographicCitation | JOURNAL OF PHYSICAL CHEMISTRY B, v.124, no.45, pp.10219 - 10225 | - |
dc.relation.isPartOf | JOURNAL OF PHYSICAL CHEMISTRY B | - |
dc.citation.title | JOURNAL OF PHYSICAL CHEMISTRY B | - |
dc.citation.volume | 124 | - |
dc.citation.number | 45 | - |
dc.citation.startPage | 10219 | - |
dc.citation.endPage | 10225 | - |
dc.description.journalClass | 1 | - |
dc.description.journalClass | 1 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Physical | - |
dc.subject.keywordPlus | CUCURBITURIL | - |