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분자활성 촉매반응 연구단
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Iridium(III)-catalyzed direct C-7 amination of indolines with organic azides

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Title
Iridium(III)-catalyzed direct C-7 amination of indolines with organic azides
Author(s)
Kwangmin Shin; Suk Bok Chang
Publication Date
2014-12
Journal
JOURNAL OF ORGANIC CHEMISTRY, v.79, no.24, pp.12197 - 12204
Publisher
AMER CHEMICAL SOC
Abstract
Iridium-catalyzed regioselective C-7 amination of indolines has been achieved with organic azides as a facile nitrogen source. The developed procedure is convenient to perform even at room temperature and applicable to a wide range of substrates with high catalytic activity. Various types of organic azides (sulfonyl, aryl, and alkyl derivatives) were all successfully reacted under the present conditions as the viable reactant. Furthermore, indoline substrates bearing easily removable N-protecting groups such as N-Boc or N-Cbz could readily be employed, highlighting the synthetic utility of this methodology.
URI
https://pr.ibs.re.kr/handle/8788114/753
ISSN
0022-3263
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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