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분자활성 촉매반응 연구단
분자활성 촉매반응 연구단
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Optical and Fluorescent Dual Sensing of Aminoalcohols by in Situ Generation of BODIPY-like Chromophore

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Title
Optical and Fluorescent Dual Sensing of Aminoalcohols by in Situ Generation of BODIPY-like Chromophore
Author(s)
Mukesh Eknath Shirbhate; Seongyeon Kwon; Ayoung Song; Seungha Kim; Dayeh Kim; Haofei Huang; Youngmee Kim; Hanna Lee; Sung-Jin Kim; Mu-Hyun Baik; Juyoung Yoon; Kwan Mook Kim
Publication Date
2020-03
Journal
ACS APPLIED MATERIALS & INTERFACES, v.142, no.11, pp.4975 - 4979
Publisher
AMER CHEMICAL SOC
Abstract
Copyright © 2020 American Chemical Society.A novel multifunctional aminophenylboronic acid connected to a diphenylketone gives both circular dichroism and fluorescence signals by in situ generation of a BODIPY-like chromophore in the presence of aminoalcohols. DFT calculations were used to understand the role of each functional group in the mechanism. This new sensor can distinguish different aminoalcohols and quantitatively indicate the concentration of the substrate, allowing for the convenient determination of the ee of racemic mixtures with a single probe.
URI
https://pr.ibs.re.kr/handle/8788114/7159
ISSN
1944-8244
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
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