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Christopher W Bielawski
다차원 탄소재료 연구단
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Bipyridyl/carbazolate silver(I) and gold(I) N-heterocyclic carbene complexes: A systematic study of geometric constraints and electronic properties

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Title
Bipyridyl/carbazolate silver(I) and gold(I) N-heterocyclic carbene complexes: A systematic study of geometric constraints and electronic properties
Author(s)
Das Adhikary S.; Mondal A.; Kisan H.K.; Christopher W. Bielawski; Dinda J.
Publication Date
2020-02
Journal
APPLIED ORGANOMETALLIC CHEMISTRY, v.34, no.2, pp.e5335 -
Publisher
WILEY
Abstract
© 2019 John Wiley & Sons, Ltd.A series of silver(I) and gold(I) carbene complexes of the type [M(L)(2,2′-bipyridine)][PF6] (L = 1-benzyl-3-(2-pyridylmethyl)benzimidazolylidene; M = Ag (1); M = Au (3)) and [M(L)(carbazole)] (M = Ag (2); M = Au (4)) were synthesized and analyzed using a range of spectroscopic and crystallographic techniques. Inspection of the solid-state structures of 1, 2 and 4 revealed a number of intermolecular noncovalent interactions. In the solid-state structure adopted by 1, π–π and Ag–Ag interactions directed the complexes to orient in a head-to-tail fashion. The photophysical properties were found to be influenced by the ancillary ligands in solution as well as in the solid-state. Calculations were performed to support the aforementioned structural and optoelectronic assignments
URI
https://pr.ibs.re.kr/handle/8788114/7003
ISSN
0268-2605
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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