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Kim, Jae Heon
나노물질 및 화학반응 연구단
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Soft-to-hard consecutive templating one-pot route from metal nitrate/phenol resin/surfactant to mesoporous metal oxides with enhanced thermal stability

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Title
Soft-to-hard consecutive templating one-pot route from metal nitrate/phenol resin/surfactant to mesoporous metal oxides with enhanced thermal stability
Author(s)
Su-Kyung Lee; Changbum Jo; Jaeheon Kim; Ryong Ryoo
Subject
Gold-supported ceria, ; Mesoporous metal oxides, ; Nanocrystalline, ; Surfactant, ; Water-gas shift reaction
Publication Date
2020-02
Journal
MICROPOROUS AND MESOPOROUS MATERIALS, v.293, pp.109767
Publisher
ELSEVIER SCIENCE BV
Abstract
© 2019Mesoporous materials with crystalline ZrO2, Y2O3, and CeO2 frameworks were one-pot synthesized from a clear solution of ethanol containing metal nitrates, organic surfactant (i.e., Pluronic® F-127), formaldehyde, and phloroglucinol. The solution was converted to a mesostructured nanocomposite of metal nitrate/phenol resin/surfactant via a solvent evaporation-induced self-assembly process. The obtained nanocomposite was calcined at 800 °C in a N2 atmosphere. X-ray powder diffraction and electron microscopic investigation revealed that the calcination caused amorphous-to-crystalline transformations in the metal oxide frameworks, while sintering to bulk metal oxides was prevented by the in-situ generated carbon component. Mesoporous metal oxides with a crystalline framework were obtained when the carbon skeleton was burnt off. The mesoporous metal oxides exhibited high BET surface areas, narrow pore-size distributions, and enhanced thermal stability. A practical benefit of the mesoporous metal oxides was demonstrated with Au/CeO2 exhibiting high catalytic activity in the water-gas-shift reaction
URI
https://pr.ibs.re.kr/handle/8788114/6993
DOI
10.1016/j.micromeso.2019.109767
ISSN
1387-1811
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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