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Yi Jiang
다차원 탄소재료 연구단
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Partial Oxidation-Induced Electrical Conductivity and Paramagnetism in a Ni(II) Tetraaza[14]annulene-Linked Metal Organic Framework

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Title
Partial Oxidation-Induced Electrical Conductivity and Paramagnetism in a Ni(II) Tetraaza[14]annulene-Linked Metal Organic Framework
Author(s)
Yi Jiang; Inseon Oh; Se Hun Joo; Onur Buyukcakir; Xiong Chen; Sun Hwa Lee; Ming Huang; Won Kyung Seong; Sang Kyu Kwak; Jung-Woo Yoo; Rodney S. Ruof
Publication Date
2019-10
Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.141, no.42, pp.16884 - 16893
Publisher
AMER CHEMICAL SOC
Abstract
© 2019 American Chemical Society.We report the synthesis and characterization of a two-dimensional (2D) conjugated Ni(II) tetraaza[14]annulene-linked metal organic framework (NiTAA-MOF) where NiTAA is a macrocyclic MN4 (M = metal, N = nitrogen) compound. The structure of NiTAA-MOF was elucidated by Fourier-transform infrared, X-ray photoemission, and X-ray diffraction spectroscopies, in combination with density functional theory (DFT) calculations. When chemically oxidized by iodine, the insulating bulk NiTAA-MOF (σ < 10-10 S/cm) exhibits an electrical conductivity of 0.01 S/cm at 300 K, demonstrating the vital role of ligand oxidation in the electrical conductivity of 2D MOFs. Magnetization measurements show that iodine-doped NiTAA-MOF is paramagnetic with weak antiferromagnetic coupling due to the presence of organic radicals of oxidized ligands and high-spin Ni(II) sites of the missing-linker defects. In addition to providing further insights into the origin of the induced electrical conductivity in 2D MOFs, both pristine and iodine-doped NiTAA-MOF synthesized in this work could find potential applications in areas such as catalase mimics, catalysis, energy storage, and dynamic nuclear polarization-nuclear magnetic resonance (DNP-NMR)
URI
https://pr.ibs.re.kr/handle/8788114/6834
ISSN
0002-7863
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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