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Tribochemistry of TaN, TiAlN and TaAlN coatings under ambient atmosphere and high-vacuum sliding conditions

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Title
Tribochemistry of TaN, TiAlN and TaAlN coatings under ambient atmosphere and high-vacuum sliding conditions
Author(s)
D. Dinesh Kumar; Revati Rani; Niranjan Kumar; Kalpataru Panda; A.M. Kamalan Kirubaharan; P. Kuppusami; R. Baskaran
Subject
Chemical bonding, ; Friction and wear, ; Microstructure, ; Tribochemistry., ; Tribolayer
Publication Date
2020-01
Journal
APPLIED SURFACE SCIENCE, v.499, pp.143989
Publisher
ELSEVIER SCIENCE BV
Abstract
© 2019 Elsevier B.V.Tribochemical analysis of monolithic TaN, TiAlN, and TaAlN coatings deposited by reactive magnetron sputtering onto 316LN stainless steel (SS) substrates are described. Tribology experiments were carried out in ambient atmospheric and high-vacuum sliding conditions to investigate the tribo-atmospheric dependent friction and wear characteristics of these coatings. The lower friction coefficient and improved wear-resistant properties were observed for TaN and TiAlN coatings in the humid atmosphere than in high-vacuum testing condition. Interestingly, lower friction and wear resistance properties of TaAlN coated SS are significantly enhanced in atmospheric as well as high-vacuum sliding conditions because of their highly dense and fine-grained microstructure with stable cubic B1 TaAlN phase. Energy dispersive X-ray spectroscopy elemental mapping and micro-focused X-ray photoelectron spectroscopy were carried out on the wear tracks to explore the comprehensive tribo-environment dependent tribochemistry. Formations of alumina (Al2O3) rich tribolayer reduced the friction and enhanced the wear resistance of TaAlN/SS sample tested in atmospheric condition; whereas this coating is highly stable in the high-vacuum condition with higher wear resistance
URI
https://pr.ibs.re.kr/handle/8788114/6677
DOI
10.1016/j.apsusc.2019.143989
ISSN
0169-4332
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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Applied Surface Science 499 (2020) 143989.pdfDownload

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