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분자활성 촉매반응 연구단
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Ru-Catalyzed Deoxygenative Regioselective C8-H Arylation of Quinoline N-Oxides

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Title
Ru-Catalyzed Deoxygenative Regioselective C8-H Arylation of Quinoline N-Oxides
Author(s)
Jinwoo Kim; Suhyeon Kim; Dongwook Kim; Sukbok Chang
Publication Date
2019-10
Journal
JOURNAL OF ORGANIC CHEMISTRY, v.84, no.20, pp.13150 - 13158
Publisher
AMER CHEMICAL SOC
Abstract
© 2019 American Chemical Society.Regioselective C-H functionalization on quinolines is of high interest to lead to value-added products. Herein, we describe the development of Ru-catalyzed deoxygenative regioselective C8 arylation of quinoline N-oxides with arylboronic esters. Mechanistic studies revealed that it proceeds in a tandem process of arylation and then deoxygenation, wherein both steps were found to be catalytic with the ruthenium species
URI
https://pr.ibs.re.kr/handle/8788114/6419
ISSN
0022-3263
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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