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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Catalytic Cascade Reaction to Access Cyclopentane-Fused Heterocycles: Expansion of Pd-TMM Cycloaddition
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- Title
- Catalytic Cascade Reaction to Access Cyclopentane-Fused Heterocycles: Expansion of Pd-TMM Cycloaddition
- Author(s)
- Donguk Ko; Seung-yeol Baek; Jae Yul Shim; Ju Young Lee; Mu-Hyun Baik; Eun Jeong Yoo
- Publication Date
- 2019-06
- Journal
- ORGANIC LETTERS, v.21, no.11, pp.3998 - 4002
- Publisher
- AMER CHEMICAL SOC
- Abstract
- © 2019 American Chemical Society.A palladium-catalyzed reaction of N-aromatic zwitterion and trimethylenemethane that gives fused N-heterocycles via dearomative [3 + 2] cycloaddition and intramolecular cyclization is developed, and a cyclopentane-fused cyclic product is generated. Combining computational and experimental studies, the site-selective dearomatization and the mechanism of this novel reaction are investigated in detail, and the value of pyridinium zwitterion as a reactant is demonstrated
- ISSN
- 1523-7060
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- B_Catalytic Casacde Reaction_orglett.9b01178.pdfDownload
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