BROWSE

Related Scientist

Researcher

강다혜
분자활성 촉매반응 연구단
more info

Regiodivergent Ring-Opening Cross-Coupling of Vinyl Aziridines with Phosphorus Nucleophiles: Access to Phosphorus-Containing Amino Acid Derivatives

Cited 0 time in webofscience Cited 0 time in scopus
11 Viewed 0 Downloaded
Title
Regiodivergent Ring-Opening Cross-Coupling of Vinyl Aziridines with Phosphorus Nucleophiles: Access to Phosphorus-Containing Amino Acid Derivatives
Author(s)
Dahye Kang; Taehwan Kim; Hyunpyo Lee; Sungwoo Hong
Publication Date
2018-12
Journal
ORGANIC LETTERS, v.20, no.23, pp.7571 - 7575
Publisher
AMER CHEMICAL SOC
Abstract
Catalytic ring-opening phosphonation and phosphatation of vinyl aziridines have been developed in a regiodivergent fashion, giving linear and branched products. Generation of P-centered radicals enables S(N)2'-type ring-opening reactions of vinyl aziridines to afford delta-amino alkylphosphorus products at room temperature. On the other hand, in situ generated phosphate anions via the Ag-catalyzed aerobic oxidation of phosphonyl reactants underwent S(N)2 reaction to provide branched phosphorus-containing amine products. Furthermore, this divergent methodology serves as a powerful tool for the stereospecific synthesis of phosphorus-containing amino acid derivatives © 2018 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/5913
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
H_Regiodivergent Ring-Opening Cross-Coupling_.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse