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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Ni-Mediated Generation of cN Unit from Formamide and Its Catalysis in the Cyanation Reactions
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- Title
- Ni-Mediated Generation of cN Unit from Formamide and Its Catalysis in the Cyanation Reactions
- Author(s)
- Luo Yang; Yu-Ting Liu; Yoonsu Park; Sung-Woo Park; Sukbok Chang
- Subject
- alkynes, ; aryl halides, ; cyano source, ; formamide, ; hydrocyanation, ; Ni catalyst
- Publication Date
- 2019-04
- Journal
- ACS CATALYSIS, v.9, no.4, pp.3360 - 3365
- Publisher
- AMER CHEMICAL SOC
- Abstract
- The in situ generation of a cyano unit from readily available organic precursors is of high interest in synthetic chemistry. Herein, we report the first example of Ni-mediated dehydration of formamide to form CN and its subsequent catalytic applications in the hydrocyanation of alkynes and cyanation of aryl halides. Formamide can serve as a convenient source for the nitrile unit, in that it releases water as the only byproduct. © 2019 American Chemical Society
- ISSN
- 2155-5435
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- acscatal.8b05111.pdfDownload
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