Ni-Mediated Generation of cN Unit from Formamide and Its Catalysis in the Cyanation Reactions
DC Field | Value | Language |
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dc.contributor.author | Luo Yang | - |
dc.contributor.author | Yu-Ting Liu | - |
dc.contributor.author | Yoonsu Park | - |
dc.contributor.author | Sung-Woo Park | - |
dc.contributor.author | Sukbok Chang | - |
dc.date.available | 2019-05-20T05:05:37Z | - |
dc.date.created | 2019-04-23 | - |
dc.date.issued | 2019-04 | - |
dc.identifier.issn | 2155-5435 | - |
dc.identifier.uri | https://pr.ibs.re.kr/handle/8788114/5815 | - |
dc.description.abstract | The in situ generation of a cyano unit from readily available organic precursors is of high interest in synthetic chemistry. Herein, we report the first example of Ni-mediated dehydration of formamide to form CN and its subsequent catalytic applications in the hydrocyanation of alkynes and cyanation of aryl halides. Formamide can serve as a convenient source for the nitrile unit, in that it releases water as the only byproduct. © 2019 American Chemical Society | - |
dc.description.uri | 1 | - |
dc.language | 영어 | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | alkynes | - |
dc.subject | aryl halides | - |
dc.subject | cyano source | - |
dc.subject | formamide | - |
dc.subject | hydrocyanation | - |
dc.subject | Ni catalyst | - |
dc.title | Ni-Mediated Generation of cN Unit from Formamide and Its Catalysis in the Cyanation Reactions | - |
dc.type | Article | - |
dc.type.rims | ART | - |
dc.identifier.wosid | 000464075700064 | - |
dc.identifier.scopusid | 2-s2.0-85063130009 | - |
dc.identifier.rimsid | 67949 | - |
dc.contributor.affiliatedAuthor | Yoonsu Park | - |
dc.contributor.affiliatedAuthor | Sung-Woo Park | - |
dc.contributor.affiliatedAuthor | Sukbok Chang | - |
dc.identifier.doi | 10.1021/acscatal.8b05111 | - |
dc.identifier.bibliographicCitation | ACS CATALYSIS, v.9, no.4, pp.3360 - 3365 | - |
dc.citation.title | ACS CATALYSIS | - |
dc.citation.volume | 9 | - |
dc.citation.number | 4 | - |
dc.citation.startPage | 3360 | - |
dc.citation.endPage | 3365 | - |
dc.description.journalClass | 1 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.subject.keywordAuthor | alkynes | - |
dc.subject.keywordAuthor | aryl halides | - |
dc.subject.keywordAuthor | cyano source | - |
dc.subject.keywordAuthor | formamide | - |
dc.subject.keywordAuthor | hydrocyanation | - |
dc.subject.keywordAuthor | Ni catalyst | - |