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Schrock vs Fischer carbenes: A quantum chemical perspective

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Title
Schrock vs Fischer carbenes: A quantum chemical perspective
Author(s)
Joonghee Won; Hoimin Jun; Manoj V. Mane; Joon Heo; Seongyeon Kwon; Mu-Hyun Baik
Publication Date
2019-01
Journal
ADVANCES IN INORGANIC CHEMISTRY, v.73, no., pp.385 - 443
Publisher
ELSEVIER ACADEMIC PRESS INC
Abstract
Early and late transition metal-carbon multiple bonds that have been widely used for many catalytic processes, organic transformations, and olefin metathesis reactions are described. Especially, the development of Schrock and Fischer type olefin metathesis catalysts aided by computational studies is discussed, focusing on work that aims at improving the reactivity, stability, and regioselectivity. The intriguing electronic feature and reactivity of a titanium alkylidyne, which leads to many unique transformations of organic molecules, are summarized. The development of Fischer type olefin metathesis catalysts to control the regioselectivity in cyclopolymerization of diynes with RuII-alkylidene catalysts employing quantum chemical studies is summarized. © 2019 Elsevier Inc.
URI
https://pr.ibs.re.kr/handle/8788114/5753
ISSN
0898-8838
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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162-M-Carbene AdvInorgChem.pdfDownload

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