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Design, synthesis and study of a photochromic alpha,omega-diene: toward new classes of photoswitchable polymers

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Title
Design, synthesis and study of a photochromic alpha,omega-diene: toward new classes of photoswitchable polymers
Author(s)
Wontae Joo; Christopher W. Bielawski
Publication Date
2019-03
Journal
ORGANIC & BIOMOLECULAR CHEMISTRY, v.17, no.9, pp.2486 - 2491
Publisher
ROYAL SOC CHEMISTRY
Abstract
A 4,5-dithienylimidazolium salt outfitted with pendant styrenyl groups was synthesized and studied. The salt was found to undergo reversible electrocyclization upon UV irradiation; subsequent exposure to visible light reversed the reaction. Acyclic diene metathesis (ADMET) polymerization of the salt afforded a novel fluorescent polyelectrolyte. © The Royal Society of Chemistry 2019
URI
https://pr.ibs.re.kr/handle/8788114/5678
DOI
10.1039/c9ob00049f
ISSN
1477-0520
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
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