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Electronic Tuning and Catalytic Activity of a Novel Pd(II) Complex Supported by a Tetracoordinate Ligand

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Title
Electronic Tuning and Catalytic Activity of a Novel Pd(II) Complex Supported by a Tetracoordinate Ligand
Author(s)
Lakshmikanta Maity; Sankar Prasad Parua; Bidyut Kumar Rana; Anvarhusein A. Isab; Christopher W. Bielawski; Joydev Dinda
Subject
Annulated carbene, ; N-heterocyclic carbene (NHC), ; Pd(II)-NHC, ; Suzuki Coupling reaction, ; TDDFT
Publication Date
2018-12
Journal
CHEMISTRYSELECT, v.3, no.46, pp.13284 - 13288
Publisher
WILEY-V C H VERLAG GMBH
Abstract
The synthesis and study of a novel Pd(II) complex (2) supported by a new tetracoordinate ligand that is based on a bis(N-heterocyclic carbene) with two pendant pyrimidinyl donors is described. The complex was characterized using a series of spectroscopic, analytical, and computational techniques. A preliminary assessment showed that 2 displayed good performance in Suzuki-Miyaura coupling reactions between phenyl boronic acid and an assortment of substituted bromobenzenes. Finally, the intrinsic electronic characteristics of the complex were elucidated through DFT-based molecular orbital calculations which revealed that the coordinated metal center was relatively electron deficient and stabilized by a series of ligand dominated interactions © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/5364
DOI
10.1002/slct.201803071
ISSN
2365-6549
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > 1. Journal Papers (저널논문)
Files in This Item:
3. Maity_et_al-2018-ChemistrySelect.pdfDownload

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