Electronic Tuning and Catalytic Activity of a Novel Pd(II) Complex Supported by a Tetracoordinate Ligand

Cited 0 time in webofscience Cited 0 time in scopus
22 Viewed 10 Downloaded
Title
Electronic Tuning and Catalytic Activity of a Novel Pd(II) Complex Supported by a Tetracoordinate Ligand
Author(s)
Lakshmikanta Maity; Sankar Prasad Parua; Bidyut Kumar Rana; Anvarhusein A. Isab; Christopher W. Bielawski; Joydev Dinda
Publication Date
2018-12
Journal
CHEMISTRYSELECT, v.3, no.46, pp.13284 - 13288
Publisher
WILEY-V C H VERLAG GMBH
Abstract
The synthesis and study of a novel Pd(II) complex (2) supported by a new tetracoordinate ligand that is based on a bis(N-heterocyclic carbene) with two pendant pyrimidinyl donors is described. The complex was characterized using a series of spectroscopic, analytical, and computational techniques. A preliminary assessment showed that 2 displayed good performance in Suzuki-Miyaura coupling reactions between phenyl boronic acid and an assortment of substituted bromobenzenes. Finally, the intrinsic electronic characteristics of the complex were elucidated through DFT-based molecular orbital calculations which revealed that the coordinated metal center was relatively electron deficient and stabilized by a series of ligand dominated interactions © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/5364
ISSN
2365-6549
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
Files in This Item:
3. Maity_et_al-2018-ChemistrySelect.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse