Supporting Nickel to Replace Platinum on Zeolite Nanosponges for Catalytic Hydroisomerization of n -Dodecane

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Title
Supporting Nickel to Replace Platinum on Zeolite Nanosponges for Catalytic Hydroisomerization of n -Dodecane
Author(s)
Jaeheon Kim; Seung Won Han; Jeong-Chul Kim; Ryong Ryoo
Publication Date
2018-11
Journal
ACS CATALYSIS, v.8, no.11, pp.10545 - 10554
Publisher
AMER CHEMICAL SOC
Abstract
Hydroisomerization of linear paraffins to branched isomers is an important petrochemical process, which commonly uses a microporous zeolite catalyst supported with Pt metal nanoparticles. Although attempts were made in the past to find an alternative to costly Pt, replacement with low-cost metals was not successful for conventional bulk zeolites, due to the low metal dispersion resulting in poor catalytic performance. Here, we demonstrate that Ni can replace Pt when it is supported on zeolites with uniform mesopores. Ni-supported MFI-,?MRE-, and TON-type zeolites possessing mesopores showed the same or even better catalytic performance in comparison to that of Pt-supported conventional MFI,?MRE, and TON zeolites, respectively. The Ni-supported zeolites exhibited even better branched isomer yields, despite low Ni loading. This result is ascribed to the confinement or sandwiching effect of Ni nanoparticles by the mesopore walls in the zeolites, which stabilizes the highly dispersed Ni nanoparticles. (c) 2018 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/5060
ISSN
2155-5435
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > Journal Papers (저널논문)
Files in This Item:
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