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분자활성 촉매반응 연구단
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Palladium(II)-Catalyzed Tandem Synthesis of Acenes Using Carboxylic Acids as Traceless Directing Groups

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Title
Palladium(II)-Catalyzed Tandem Synthesis of Acenes Using Carboxylic Acids as Traceless Directing Groups
Author(s)
Kiho Kim; Dhananjayan Vasu; Honggu Im; Sungwoo Hong
Publication Date
2016-07
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.55, no.30, pp.8652 - 8655
Publisher
WILEY-V C H VERLAG GMBH
Abstract
A straightforward synthetic strategy for generating useful anthracene derivatives was developed involving palladium(II)-catalyzed tandem transformation with carboxylic acids as traceless directing groups. Carboxyl-directed C-H alkenylation, carboxyl-directed secondary C-H activation and rollover, intramolecular C-C bond formation, and decarboxylative aromatization are proposed as the key steps in the tandem reaction pathway. This novel synthetic route utilizes a broad range of substrates and provides a convenient synthetic tool that allows access to acenes (c) 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/4835
ISSN
1433-7851
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
Hong_Kim_et_al-2016-Angewandte_Chemie_International_Edition (1).pdfDownload

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