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Catalytic Dearomatization of N-Heteroarenes with Silicon and Boron Compounds

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Title
Catalytic Dearomatization of N-Heteroarenes with Silicon and Boron Compounds
Author(s)
Sehoon Park; Sukbok Chang
Publication Date
2017-06
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.56, no.27, pp.7720 - 7738
Publisher
WILEY-V C H VERLAG GMBH
Abstract
Dearomatized N-heterocycles are an important class of structural motifs for organic synthesis and chemical biology. The catalytic dearomative reduction of unactivated N-heteroarenes using silicon and/or boron-containing compounds as a reductant is one of the most straightforward alternatives to hydrogenation. However, thus far, there are few reported examples on the catalytic reduction of N-heteroaromatic compounds with silane or borane reducing agents. This Review presents recent advances in the catalytic reduction of unactivated N-heteroarenes by hydrosilanes, hydroboranes, silaboranes, and diboranes. The focus is on the chemical reactivity and selectivity of transition-metal or metal-free organocatalyst systems. In addition, the working modes of these catalysis will be described primarily on the basis of experimental mechanistic insight. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinhei
URI
https://pr.ibs.re.kr/handle/8788114/3955
ISSN
1433-7851
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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