Transition Metal-Catalyzed C-H Amination: Scope, Mechanism, and ApplicationsHighly Cited Paper
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Title
- Transition Metal-Catalyzed C-H Amination: Scope, Mechanism, and Applications
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Author(s)
- Yoonsu Park; Youyoung Kim; Sukbok Chang
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Publication Date
- 2017-07
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Journal
- CHEMICAL REVIEWS, v.117, no.13, pp.9247 - 9301
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Publisher
- AMER CHEMICAL SOC
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Abstract
- Catalytic transformation of ubiquitous C-H bonds into valuable C-N bonds offers an efficient synthetic approach to construct N-functionalized molecules. Over the last few decades, transition metal catalysis has been repeatedly proven to be a powerful tool for the direct conversion of cheap hydrocarbons to synthetically versatile amino-containing compounds. This Review comprehensively highlights recent advances in intra- and intermolecular C-H amination reactions utilizing late transition metal-based catalysts. Initial discovery, mechanistic study, and additional applications were categorized on the basis of the mechanistic scaffolds and types of reactions. Reactivity and selectivity of novel systems are discussed in three sections, with each being defined by a proposed working mode. © 2017 American Chemical Society
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URI
- https://pr.ibs.re.kr/handle/8788114/3954
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DOI
- 10.1021/acs.chemrev.6b00644
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ISSN
- 0009-2665
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Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
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