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분자활성 촉매반응 연구단
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Transition Metal-Catalyzed C-H Amination: Scope, Mechanism, and Applications Highly Cited Paper Hot Paper

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Title
Transition Metal-Catalyzed C-H Amination: Scope, Mechanism, and Applications
Author(s)
Yoonsu Park; Youyoung Kim; Sukbok Chang
Publication Date
2017-07
Journal
CHEMICAL REVIEWS, v.117, no.13, pp.9247 - 9301
Publisher
AMER CHEMICAL SOC
Abstract
Catalytic transformation of ubiquitous C-H bonds into valuable C-N bonds offers an efficient synthetic approach to construct N-functionalized molecules. Over the last few decades, transition metal catalysis has been repeatedly proven to be a powerful tool for the direct conversion of cheap hydrocarbons to synthetically versatile amino-containing compounds. This Review comprehensively highlights recent advances in intra- and intermolecular C-H amination reactions utilizing late transition metal-based catalysts. Initial discovery, mechanistic study, and additional applications were categorized on the basis of the mechanistic scaffolds and types of reactions. Reactivity and selectivity of novel systems are discussed in three sections, with each being defined by a proposed working mode. © 2017 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/3954
ISSN
0009-2665
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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