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분자활성 촉매반응 연구단
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Direct Phosphonation of Quinolinones and Coumarins Driven by the Photochemical Activity of Substrates and Products

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Title
Direct Phosphonation of Quinolinones and Coumarins Driven by the Photochemical Activity of Substrates and Products
Author(s)
Inwon Kim; Minsik Min; Dahye Kang; Kiho Kim; Sungwoo Hong
Publication Date
2017-03
Journal
ORGANIC LETTERS, v.19, no.6, pp.1394 - 1397
Publisher
AMER CHEMICAL SOC
Abstract
Light-promoted phosphonation of quinolinones and coumarins was developed without the need for an external photocatalyst. Investigations support a mechanism whereby both starting materials and products act as photosensitizers upon excitation using compact fluorescent light sources to photochemically promote the dissociation of the N-O bond in the pyridinium salt by a single electron transfer pathway. A wide range of quinolinone and coumarin substrates can be utilized in the phosphonation process under mild reaction conditions. © 2017 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/3750
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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