BROWSE

Related Scientist

Researcher

분자활성 촉매반응 연구단
분자활성 촉매반응 연구단
more info

Novel intramolecular π-π-interaction in a BODIPY system by oxidation of a single selenium center: geometrical stamping and spectroscopic and spectrometric distinctions

Cited 4 time in webofscience Cited 0 time in scopus
112 Viewed 3 Downloaded
Title
Novel intramolecular π-π-interaction in a BODIPY system by oxidation of a single selenium center: geometrical stamping and spectroscopic and spectrometric distinctions
Author(s)
Youngsam Kim; Taehong Jun; Sandip V. Mulay; Sudesh T. Manjare; Jinseong Kwak; Yunho Lee; David G. Churchill
Publication Date
2017-03
Journal
DALTON TRANSACTIONS, v.46, no.12, pp.4111 - 4117
Publisher
ROYAL SOC CHEMISTRY
Abstract
A new BODIPY system displaying an intramolecular π-π-interaction was synthesized and studied. When the selenium center was oxidized, the substituted phenyl group undergoes π-π stacking with one side of the BODIPY core. The oxidized form showed, not only a down-field shift in the NMR peak, but also splitting due to geometrical changes that arise when going from Cs to C1. The compound was characterized by X-ray diffraction; DFT methods helped elucidate the influence of the unexpected π-π stack and its connection to the photophysical properties imparted by the Se oxidation. © The Royal Society of Chemistry
URI
https://pr.ibs.re.kr/handle/8788114/3747
ISSN
1477-9226
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
Files in This Item:
201703_novelintramolecular.pdfDownload

qrcode

  • facebook

    twitter

  • Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.
해당 아이템을 이메일로 공유하기 원하시면 인증을 거치시기 바랍니다.

Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.

Browse