Tailoring Photoelectrochemical Performance and Stability of Cu(In,Ga)Se2 Photocathode via TiO2-Coupled Buffer Layers
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- Tailoring Photoelectrochemical Performance and Stability of Cu(In,Ga)Se2 Photocathode via TiO2-Coupled Buffer Layers
- Bonhyeong Koo; Sung-Wook Nam; Richard Haight; Suncheul Kim; Seungtaeg Oh; Minhyung Cho; Jihun Oh; Jeong Yong Lee; Byung Tae Ahn; Byungha Shin
- ACS APPLIED MATERIALS & INTERFACES, v.9, no.6, pp.5279 - 5287
- AMER CHEMICAL SOC
- We report on the photoelectrochemical (PEC) performance and stability of Cu(In,Ga)Se2 (CIGS)-based photocathodes for photocatalytic hydrogen evolution from water. Various functional overlayers, such as CdS, TiO2, ZnxSnyOz, and a combination of the aforementioned, were applied on the CIGS to improve the performance and stability. We identified that the insertion of TiO2 overlayer on p-CIGS/n-buffer layers significantly improves the PEC performance. A multilayered photocathode consisting of CIGS/CdS/TiO2/Pt exhibited the best current-potential characteristics among the tested photocathodes, which demonstrates a power-saved efficiency of 2.63%. However, repeated linear sweep voltammetry resulted in degradation of performance. In this regard, we focused on the PEC durability issues through in-depth chemical characterization that revealed the degradation was attributed to atomic redistribution of elements constituting the photocathode, namely, in-diffusion of Pt catalysts, out-diffusion of elements from the CIGS, and removal of the metal-oxide layers; the best-performing CIGS/CdS/TiO2/Pt photocathode retained its initial performance until the TiO2 overlayer was removed. It was also found that the durability of CIGS photocathodes with a TiO2-coated metal-oxide buffer layer such as ZnxSnyOz was better than those with a TiO2-coated CdS, and the degradation mechanism was different, suggesting that the stability of a CIGS-based photocathode can be improved by careful design of the structure. © 2017 American Chemical Society
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