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나노물질및화학반응연구단
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Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive

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dc.contributor.authorKyungjun Kang-
dc.contributor.authorJaewook Kim-
dc.contributor.authorAnsoo Lee-
dc.contributor.authorWoo Youn Kim-
dc.contributor.authorHyunwoo Kim-
dc.date.available2017-01-20T08:32:32Z-
dc.date.created2016-02-19-
dc.date.issued2016-02-
dc.identifier.issn1523-7060-
dc.identifier.urihttps://pr.ibs.re.kr/handle/8788114/3314-
dc.description.abstractA mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite (briphos) ligand together with Pd(dba)2 is a highly efficient catalyst, and an acid additive involved in the rate-determining step promotes the catalytic cycle. The coupling reaction of allylic alcohols with N-heterocycles including imidazoles, benzimidazoles, and triazole proceeds under mild reaction conditions with high yields using Pd/briphos and pentafluorophenol. © 2016 American Chemical Society-
dc.description.uri1-
dc.language영어-
dc.publisherAMER CHEMICAL SOC-
dc.titlePalladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid Additive-
dc.typeArticle-
dc.type.rimsART-
dc.identifier.wosid000369771800069-
dc.identifier.scopusid2-s2.0-84957599473-
dc.identifier.rimsid22380-
dc.date.tcdate2018-10-01-
dc.contributor.affiliatedAuthorHyunwoo Kim-
dc.identifier.doi10.1021/acs.orglett.6b00001-
dc.identifier.bibliographicCitationORGANIC LETTERS, v.18, no.3, pp.616 - 619-
dc.citation.titleORGANIC LETTERS-
dc.citation.volume18-
dc.citation.number3-
dc.citation.startPage616-
dc.citation.endPage619-
dc.date.scptcdate2018-10-01-
dc.description.wostc11-
dc.description.scptc12-
dc.description.journalClass1-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
Appears in Collections:
Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > 1. Journal Papers (저널논문)
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Org. Lett. 2016, 18, 616−619.pdfDownload

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