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분자활성 촉매반응 연구단
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A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C-H Amidation Using Azidoformates

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Title
A Facile Access to Primary Alkylamines and Anilines via Ir(III)-Catalyzed C-H Amidation Using Azidoformates
Author(s)
Hyunwoo Kim; Gyeongtae Park; Juhyeon Park; Sukbok Chang
Publication Date
2016-09
Journal
ACS CATALYSIS, v.6, no.9, pp.5922 - 5929
Publisher
AMER CHEMICAL SOC
Abstract
Described herein is the development of Ir(III)-catalyzed direct C-H amidation using azidoformates as a readily deprotectable amino source. Substrates with unactivated methyl C(sp3)-H and aromatic or olefinic C(sp2)-H bonds were smoothly reacted by the iridium-based catalyst system to provide the corresponding primary alkylamines and anilines upon the subsequent removal of N-protecting groups, such as Boc, Fmoc, Cbz, pNZ, or Troc. A brief mechanistic study and synthetic applications are also presented. © 2016 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/3274
ISSN
2155-5435
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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