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나노물질 및 화학반응 연구단
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A facile method for the selective decoration of graphene defects based on a galvanic displacement reaction

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dc.contributor.authorHong J.ko
dc.contributor.authorLee J.-B.ko
dc.contributor.authorLee S.ko
dc.contributor.authorSeo J.ko
dc.contributor.authorHyunsoo Leeko
dc.contributor.authorJeong Young Parkko
dc.contributor.authorAhn J.-H.ko
dc.contributor.authorSeo T.I.ko
dc.contributor.authorLee T.ko
dc.contributor.authorLee H.-B.-R.ko
dc.date.available2017-01-06T02:06:07Z-
dc.date.created2016-08-19ko
dc.date.issued201604ko
dc.identifier.issn1884-4049ko
dc.identifier.urihttp://pr.ibs.re.kr/handle/8788114/3175ko
dc.description.abstractInherent defects, such as grain boundaries (GBs), wrinkles and structural cracks, present on chemical vapor deposition (CVD)-grown graphene are inevitable because of the mechanism used for its synthesis. Because graphene defects are detrimental to electrical transport properties and degrade the performance of graphene-based devices, a defect-healing process is required. We report a simple and effective approach for enhancing the electrical properties of graphene by selective graphene-defect decoration with Pd nanoparticles (Pd NPs) using a wet-chemistry-based galvanic displacement reaction. According to the selective nucleation and growth behaviors of Pd NPs on graphene, several types of defects, such as GBs, wrinkles, graphene regions on Cu fatigue cracks and external edges of multiple graphene layers, were precisely confirmed via spherical aberration correction scanning transmission electron microscopy, field-emission scanning electron microscopy and atomic force microscopy imaging. The resultant Pd-NP-decorated graphene films showed improved sheet resistance. A transparent heater was fabricated using Pd-decorated graphene films and exhibited better heating performance than a heater fabricated using pristine graphene. This simple and novel approach promises the selective decoration of defects in CVD-grown graphene and further exploits the visualization of diverse defects on a graphene surface, which can be a versatile method for improving the properties of graphene.ko
dc.languageENGko
dc.publisherNATURE PUBLISHING GROUPko
dc.titleA facile method for the selective decoration of graphene defects based on a galvanic displacement reactionko
dc.typeARTICLEko
dc.type.rimsAko
dc.identifier.wosid000379671900005ko
dc.identifier.scopusid2-s2.0-84979518447ko
dc.identifier.pid649null
dc.identifier.pid401null
dc.description.wostc8-
dc.date.scptcdate2018-10-01-
dc.identifier.doi10.1038/am.2016.42ko
dc.identifier.bibliographicCitationNPG ASIA MATERIALS, v.8, no., pp.e262 -ko
dc.date.tcdate2018-10-01-
dc.description.scptc8-
dc.type.docTypeArticle-
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Center for Nanomaterials and Chemical Reactions(나노물질 및 화학반응 연구단) > Journal Papers (저널논문)
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