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분자활성 촉매반응 연구단
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Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway

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Title
Rhodium-catalyzed selective C-H functionalization of NNN tridentate chelating compounds via a rollover pathway
Author(s)
Seung Youn Hong; Jaesung Kwak; Sukbok Chang
Publication Date
2016-02
Journal
CHEMICAL COMMUNICATIONS, v.52, no.15, pp.3159 - 3162
Publisher
ROYAL SOC CHEMISTRY
Abstract
Reported herein is the first example of the Rh(NHC)-catalyzed selective bis C-H alkylation of NNN tridentate chelating compounds in reaction with alkenes. The observed excellent site-selectivity can readily be explained by the postulated rollover pathway in the C-H bond activation step. The reaction is highly facile affording bis-alkylated tridentate products in high yields over a broad range of versatile heteroarene substrates and alkene reactants including ethylene gas, thus enabling its applications to be feasible in coordination and synthetic chemistry. © The Royal Society of Chemistry 2016
URI
https://pr.ibs.re.kr/handle/8788114/2645
ISSN
1359-7345
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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