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분자활성 촉매반응 연구단
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A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C-H Amidation of N-Pivaloylindoles with Organic Azides

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Title
A Direct Access to 7-Aminoindoles via Iridium-Catalyzed Mild C-H Amidation of N-Pivaloylindoles with Organic Azides
Author(s)
Youyoung Kim; Juhyeon Park; Sukbok Chang
Publication Date
2016-04
Journal
ORGANIC LETTERS, v.18, no.8, pp.1892 - 1895
Publisher
AMER CHEMICAL SOC
Abstract
Ir(III)-catalyzed regioselective direct C-7 amidation of indoles in reaction with organic azides has been developed. While its efficiency was varied by the choice of N-directing groups, N-pivaloylindoles were most effective in undergoing the desired amidation at room temperature over a broad range of substrates. The reaction was scalable, and deprotection of the chelation group was also facile. © 2016 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/2641
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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