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Malleswara Rao Kuram
유전체 항상성 연구단
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Copper-Catalyzed Direct Synthesis of 1,2,4-Oxadiazoles from Amides and Organic Nitriles by Oxidative N-O Bond Formation

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Title
Copper-Catalyzed Direct Synthesis of 1,2,4-Oxadiazoles from Amides and Organic Nitriles by Oxidative N-O Bond Formation
Author(s)
Malleswara Rao Kuram; Woo Gyum Kim; Kyungjae Myung; Sung You Hong
Publication Date
2016-01
Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, v.2016, no.3, pp.438 - 442
Publisher
WILEY-V C H VERLAG GMBH
Abstract
Herein, we report the first Cu-catalyzed one-step method for the synthesis of 1,2,4-oxadiazoles from stable, less toxic, and readily available amides and organic nitriles by a rare oxidative N-O bond formation using O-2 as sole oxidant. This method has a broad substrate scope and a good tolerance for diverse functional groups. Moreover, the synthetic utility of this method is highlighted by the synthesis of biologically active 3,5-disubstituted derivatives. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/2493
ISSN
1434-193X
Appears in Collections:
Center for Genomic Integrity(유전체 항상성 연구단) > Journal Papers (저널논문)
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