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Christopher W Bielawski
다차원 탄소재료 연구단
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Post-polymerization modification of poly(vinyl ether)s: a Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s

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Title
Post-polymerization modification of poly(vinyl ether)s: a Ru-catalyzed oxidative synthesis of poly(vinyl ester)s and poly(propenyl ester)s
Author(s)
Di Liu; Christopher W. Bielawski
Publication Date
2016-01
Journal
POLYMER CHEMISTRY, v.7, no.1, pp.63 - 68
Publisher
ROYAL SOC CHEMISTRY
Abstract
Poly(vinyl ester)s were readily prepared via a ruthenium catalyzed C-H oxidation of the corresponding poly(vinyl ether)s under mild conditions. The transformations were efficient and in many cases proceeded without significant chain cleavage. The method was also successfully used to prepare high molecular weight poly(propenyl ester) for the first time as well as a polyester with a relatively high content (>50%) of gamma-butyrolactone repeat unit from poly(tetrahydrofuran). The polymeric products were characterized via FT-IR spectroscopy, NMR spectroscopy, gel permeation chromatography, and other techniques
URI
https://pr.ibs.re.kr/handle/8788114/2409
ISSN
1759-9954
Appears in Collections:
Center for Multidimensional Carbon Materials(다차원 탄소재료 연구단) > Journal Papers (저널논문)
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