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분자활성 촉매반응 연구단
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Iridium-Catalyzed Direct C-H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle

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Title
Iridium-Catalyzed Direct C-H Amination with Alkylamines: Facile Oxidative Insertion of Amino Group into Iridacycle
Author(s)
Hyunwoo Kim; Sukbok Chang
Publication Date
2015-11
Journal
ACS CATALYSIS, v.5, no.11, pp.6665 - 6669
Publisher
AMER CHEMICAL SOC
Abstract
Described herein is the development of Cp∗Ir(III)-catalyzed direct arene C-H amination using alkylamines as an amino source. This C-N bond formation showcases a notable example of cross-dehydrogenative coupling to install an amino functionality at the ortho-position of benzamide substrates. Mechanistic studies including the isolation of an amine-bound iridacyclic intermediate along with a set of chemical oxidations demonstrated the Ir-catalyzed inner-sphere C-H amination with primary alkylamines for the first time. © 2015 American Chemical Society
URI
https://pr.ibs.re.kr/handle/8788114/2265
ISSN
2155-5435
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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