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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)
Metal-Free Hydrosilylation Polymerization by Borane Catalyst
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- Title
- Metal-Free Hydrosilylation Polymerization by Borane Catalyst
- Author(s)
- Dong Wook Kim; Seewon Joung; Jeung Gon Kim; Sukbok Chang
- Subject
- borane catalyst · hydrosilylation ·metal-free catalysis · polycarbosilanes · polymerization
- Publication Date
- 2015-12
- Journal
- ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.54, no.49, pp.14805 - 14809
- Publisher
- WILEY-V C H VERLAG GMBH
- Abstract
- The first example of metal-free hydrosilylation polymerization between dienes and disilanes is developed by using a borane catalyst, B(C6F5)3 to replace precious transitionmetal- based systems. Under the easy-to-handle and mild conditions, a step-growth polymerization of two readily available diene and disilane units was achieved with high degrees of polymerization. Various combinations of dienes and disilanes produced polycarbosilanes with a broad range of structures and properties. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1433-7851
- Appears in Collections:
- Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > 1. Journal Papers (저널논문)
- Files in This Item:
- Metal-Free Hydrosilylation Polymerization by Borane Catalyst.pdfDownload
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