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분자활성 촉매반응 연구단
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Metal-Free Hydrosilylation Polymerization by Borane Catalyst

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Title
Metal-Free Hydrosilylation Polymerization by Borane Catalyst
Author(s)
Dong Wook Kim; Seewon Joung; Jeung Gon Kim; Sukbok Chang
Publication Date
2015-12
Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, v.54, no.49, pp.14805 - 14809
Publisher
WILEY-V C H VERLAG GMBH
Abstract
The first example of metal-free hydrosilylation polymerization between dienes and disilanes is developed by using a borane catalyst, B(C6F5)3 to replace precious transitionmetal- based systems. Under the easy-to-handle and mild conditions, a step-growth polymerization of two readily available diene and disilane units was achieved with high degrees of polymerization. Various combinations of dienes and disilanes produced polycarbosilanes with a broad range of structures and properties. © 2015 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
URI
https://pr.ibs.re.kr/handle/8788114/2214
ISSN
1433-7851
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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