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분자활성 촉매반응 연구단
분자활성 촉매반응 연구단
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Rh(iii)-catalyzed direct C-H/C-H cross-coupling of quinones with arenes assisted by a directing group: Identification of carbazole quinones as GSKβ inhibitors

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Title
Rh(iii)-catalyzed direct C-H/C-H cross-coupling of quinones with arenes assisted by a directing group: Identification of carbazole quinones as GSKβ inhibitors
Author(s)
Youngtaek Moon; Yujeong Jeong; Daehyuk Kook; Sungwoo Hong
Publication Date
2015-04
Journal
ORGANIC & BIOMOLECULAR CHEMISTRY, v.13, no.13, pp.3918 - 3923
Publisher
ROYAL SOC CHEMISTRY
Abstract
Rh-catalyzed direct C-H/C-H cross-coupling reaction of various (hetero)arenes with quinones is developed. This protocol is effective for a broad range of both quinone and arene substrates and a wide range of directing groups for this reaction, affording structurally diverse aryl-substituted quinones with high synthetic utility. Moreover, the present synthetic route allowed for the rapid construction of the carbazole quinone moiety that was identified as a new inhibitor scaffold for GSKβ. This journal is © The Royal Society of Chemistry 2015
URI
https://pr.ibs.re.kr/handle/8788114/2047
ISSN
1477-0520
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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