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Wang Zhen
분자활성 촉매반응 연구단
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Copper-mediated transformation of organosilanes to nitriles with DMF and ammonium iodide

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Title
Copper-mediated transformation of organosilanes to nitriles with DMF and ammonium iodide
Author(s)
Zhen Wang; Chang S.
Publication Date
2013-04
Journal
ORGANIC LETTERS, v.15, no.8, pp.1990 - 1993
Publisher
AMER CHEMICAL SOC
Abstract
Cyanation of aryl-, diaryldimethyl-, and styrylsilanes was developed for the first time under copper-mediated oxidative conditions using ammonium iodide and DMF as the combined source of nitrogen and carbon atom of the introduced cyano unit, respectively. The reaction was observed to proceed in a two-step process: initial conversion of organosilanes to their iodo intermediates and then cyanation. This method has a broad substrate scope with high functional group tolerance. © 2013 American Chemical Society.
URI
https://pr.ibs.re.kr/handle/8788114/1353
ISSN
1523-7060
Appears in Collections:
Center for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단) > Journal Papers (저널논문)
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