IBS Publications Repository: Copper-mediated transformation of organosilanes to nitriles with DMF and ammonium iodide

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IBS Publications RepositoryCenter for Catalytic Hydrocarbon Functionalizations(분자활성 촉매반응 연구단)1. Journal Papers (저널논문)

Copper-mediated transformation of organosilanes to nitriles with DMF and ammonium iodide

DC Field	Value	Language
dc.contributor.author	Zhen Wang	-
dc.contributor.author	Chang S.	-
dc.date.available	2015-04-20T07:06:39Z	-
dc.date.created	2014-09-12	-
dc.date.issued	2013-04	-
dc.identifier.issn	1523-7060	-
dc.identifier.uri	https://pr.ibs.re.kr/handle/8788114/1353	-
dc.description.abstract	Cyanation of aryl-, diaryldimethyl-, and styrylsilanes was developed for the first time under copper-mediated oxidative conditions using ammonium iodide and DMF as the combined source of nitrogen and carbon atom of the introduced cyano unit, respectively. The reaction was observed to proceed in a two-step process: initial conversion of organosilanes to their iodo intermediates and then cyanation. This method has a broad substrate scope with high functional group tolerance. © 2013 American Chemical Society.	-
dc.description.uri	1	-
dc.language	영어	-
dc.publisher	AMER CHEMICAL SOC	-
dc.subject	ammonium iodide	-
dc.subject	copper	-
dc.subject	nitrile	-
dc.subject	quaternary ammonium derivative	-
dc.subject	silane derivative	-
dc.subject	article	-
dc.subject	catalysis	-
dc.subject	chemical structure	-
dc.subject	chemistry	-
dc.subject	combinatorial chemistry	-
dc.subject	oxidation reduction reaction	-
dc.subject	synthesis	-
dc.subject	Catalysis	-
dc.subject	Combinatorial Chemistry Techniques	-
dc.subject	Copper	-
dc.subject	Molecular Structure	-
dc.subject	Nitriles	-
dc.subject	Oxidation-Reduction	-
dc.subject	Quaternary Ammonium Compounds	-
dc.subject	Silanes	-
dc.title	Copper-mediated transformation of organosilanes to nitriles with DMF and ammonium iodide	-
dc.type	Article	-
dc.type.rims	ART	-
dc.identifier.wosid	000318001400051	-
dc.identifier.scopusid	2-s2.0-84876579692	-
dc.identifier.rimsid	54072	ko
dc.date.tcdate	2018-10-01	-
dc.contributor.affiliatedAuthor	Zhen Wang	-
dc.contributor.affiliatedAuthor	Chang S.	-
dc.identifier.doi	10.1021/ol400659p	-
dc.identifier.bibliographicCitation	ORGANIC LETTERS, v.15, no.8, pp.1990 - 1993	-
dc.citation.title	ORGANIC LETTERS	-
dc.citation.volume	15	-
dc.citation.number	8	-
dc.citation.startPage	1990	-
dc.citation.endPage	1993	-
dc.date.scptcdate	2018-10-01	-
dc.description.wostc	43	-
dc.description.scptc	45	-
dc.description.journalClass	1	-
dc.description.journalRegisteredClass	scie	-
dc.description.journalRegisteredClass	scopus	-